Transcription

Safety Data SheetDRA90485according to Hazard Communication Standard; 29 CFR 1910.1200DRANO LIQUID DRAIN CLEANERVersion 1.2Print Date 03/04/2015Revision Date 02/24/2015SDS Number 3500000042981. PRODUCT AND COMPANY IDENTIFICATIONProduct informationProduct name:DRANO LIQUID DRAIN CLEANERRecommended use:Drain CleanerManufacturer, importer,supplier:S.C. Johnson & Son, Inc.1525 Howe StreetRacine WI 53403-2236TelephoneEmergency telephonenumber:: 1800558525224 Hour Medical Emergency Phone: (866)231-540624 Hour International Emergency Phone: (703)527-388724 Hour Transport Emergency Phone: (800)424-93002. HAZARDS IDENTIFICATIONClassification of the substance or mixtureGlobally Harmonized System (GHS) ClassificationHazard classificationHazard categoryCorrosive to metalsCategory 1Skin corrosionCategory 1BSerious eye damageCategory 1Hazards identificationMay be corrosive to metals.Causes severe skin burns andeye damage.Causes serious eye damage.LabellingHazard symbolsCorrosionSignal wordDangerHazard statementsMay be corrosive to metals.Causes severe skin burns and eye damage.Precautionary statementsIf medical advice is needed, have product container or label at hand.Keep out of reach of children.Read label before use.Immediately call a POISON CENTER or doctor/ physician.Specific treatment (see supplemental first aid instructions on this label).1/13

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200DRANO LIQUID DRAIN CLEANERVersion 1.2Print Date 03/04/2015Revision Date 02/24/2015SDS Number 350000004298IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easyto do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Wash contaminated clothing before reuse.Absorb spillage to prevent material damage.Store locked up.Store in corrosive resistant polypropylene container with a resistant inner liner.Store in corrosive resistant polyethylene container with a resistant inner liner.Store in corrosive resistant stainless steel container with a resistant inner liner.Store in corrosive resistant aluminium container with a resistant inner liner.Dispose of contents/ container to an approved incineration plant.Keep only in original container.Wear protective gloves.Do not breathe dust or mist.Wash hands thoroughly after handling.Other hazards: None identified3. COMPOSITION/INFORMATION ON INGREDIENTSChemical NameCAS-No.Weight percentSodium hypochlorite7681-52-91.00 - 5.00Sodium chloride7647-14-51.00 - 5.00Sodium hydroxide1310-73-21.00 - 5.00Sodium silicate1344-09-81.00 - 5.00The specific chemical identity and/or exact percentage (concentration) of this composition has beenwithheld as a trade secret.For additional information on product ingredients, see www.whatsinsidescjohnson.com.4. FIRST AID MEASURESEye contact:IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continuerinsing. Immediately call a POISON CENTER or doctor/physician. Get medical attention immediately.Skin contact:IF ON SKIN (or hair): Take off immediately all contaminated2/13

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200DRANO LIQUID DRAIN CLEANERVersion 1.2Print Date 03/04/2015Revision Date 02/24/2015SDS Number 350000004298clothing. Rinse skin with water/shower. Wash contaminatedclothing before reuse. Immediately call a POISON CENTER ordoctor/ physician.Inhalation:IF INHALED: If breathing is difficult, remove victim to fresh airand keep at rest in a position comfortable for breathing.Ingestion:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Suitable extinguishingmedia:Use water spray, alcohol-resistant foam, dry chemical orcarbon dioxide.Specific hazards duringfirefightingSpecial protectiveequipment for firefighters:Container may melt and leak in heat of fire.:Wear suitable protective clothing and gloves.Further information:Wear full protective clothing and positive pressure selfcontained breathing apparatus. In case of fire and/or explosiondo not breathe fumes.5. FIREFIGHTING MEASURES6. ACCIDENTAL RELEASE MEASURESPersonal precautions:Wear personal protective equipment.Wash thoroughly after handling.Environmentalprecautions:Outside of normal use, avoid release to the environment.Methods and materialsfor containment andcleaning up:Dike large spills.Clean residue from spill site.Absorb spillage to prevent material damage.:Avoid contact with skin, eyes and clothing.For personal protection see section 8.7. HANDLING AND STORAGEHandlingPrecautions for safehandling3/13

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200DRANO LIQUID DRAIN CLEANERVersion 1.2Print Date 03/04/2015Revision Date 02/24/2015SDS Number 350000004298Use only as directed.KEEP OUT OF REACH OF CHILDREN AND PETS.Avoid breathing vapours, mist or gas.Wash thoroughly after handling.Advice on protectionagainst fire and explosion:Normal measures for preventive fire protection.:Keep container closed when not in use.Store locked up.Store in original container.Store in corrosive resistant aluminium container with a resistantinner liner.StorageRequirements for storageareas and containers8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational Exposure LimitsComponentsCAS-No.mg/m3ppmSodium hydroxide1310-73-22 mg/m3-Nonstandardunits-Sodium hydroxide1310-73-22 mg/m3--BasisOSHA TWAACGIHCeilingPersonal protective equipmentRespiratory protection:Use only with adequate ventilation.Substantial amounts of mist/vapors can be controlled withlocal exhaust ventilation or respiratory protection.Hand protection:Rubber glovesEye protection:Wear splash-resistant Chemical goggles.Skin and body protection:Protective footwear.Hygiene measures:Handle in accordance with good industrial hygiene and safetypractice. Wash thoroughly after handling.4/13

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200DRANO LIQUID DRAIN CLEANERVersion 1.2Print Date 03/04/2015Revision Date 02/24/2015SDS Number 3500000042989. PHYSICAL AND CHEMICAL PROPERTIESForm:liquidColor:natural colourOdor:BleachOdour Threshold: No data availablepH: 11.5 - 13.4Melting point/freezing point: No data availableInitial boiling point andboiling range: 93 CFlash point: Not applicableEvaporation rate: No data availableFlammability (solid, gas): No data availableUpper/lower flammability orexplosive limits: Not applicableVapour pressure: similar to waterVapour density: No data availableRelative density: 1.09 g/cm3 at 25 CSolubility(ies): completely soluble5/13

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200DRANO LIQUID DRAIN CLEANERVersion 1.2Print Date 03/04/2015Revision Date 02/24/2015SDS Number 350000004298Partition coefficient: noctanol/water: Not applicableAuto-ignition temperature: Not applicableDecomposition temperature: No data availableViscosity, dynamic: No data availableViscosity, kinematic: No data availableOxidizing properties: No data availableVolatile OrganicCompoundsTotal VOC (wt. %)*:Other information: None identified0 % - additional exemptions may apply*as defined by US Federal and State Consumer ProductRegulations10. STABILITY AND REACTIVITYPossibility of hazardousreactions: If accidental mixing occurs and toxic gas is formed, exit areaimmediately. Do not return until well ventilated.Conditions to avoid: Direct sources of heat.Incompatible materials: Do not mix with bleach or any other household cleaners.Strong basesHazardous decompositionproducts: Thermal decomposition can lead to release of irritating gasesand vapours.11. TOXICOLOGICAL INFORMATION6/13:

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200DRANO LIQUID DRAIN CLEANERVersion 1.2Print Date 03/04/2015Revision Date 02/24/2015SDS Number 350000004298Emergency Overview:DangerAcute oral toxicity:LD50estimated 5,000 mg/kgCauses severe digestive tract burns.Acute inhalation toxicity:No data availableAcute dermal toxicity:LD50estimated 2,000 mg/kgGHS PropertiesAcute toxicityClassificationNo classification proposedSkin corrosionCategory 1B-Serious eye damageCategory 1-Skin sensitisationNo classification proposed-RespiratorysensitisationGerm cell mutagenicityNo classification proposed-No classification proposed-CarcinogenicityNo classification proposed-Reproductive toxicityNo classification proposed-Specific target organtoxicity - singleexposureSpecific target organtoxicity - repeatedexposureAspiration hazardNo classification proposed-No classification proposed-No classification proposed-Aggravated MedicalCondition:Routes of entry-Individuals with chronic respiratory disorders such as asthma,chronic bronchitis, emphysema, etc. may be more susceptibleto irritating effects7/13

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200DRANO LIQUID DRAIN CLEANERVersion 1.2Print Date 03/04/2015Revision Date 02/24/2015SDS Number 35000000429812. ECOLOGICAL INFORMATIONProduct : The product itself has not been tested.ToxicityThe ingredients in this formula have been reviewed and no adverse impact to the environment isexpected when used according to label directions.Toxicity to fishComponentsEnd pointSpeciesValueSodium hypochloritesemistatic testLC50Oncorhynchus mykiss(rainbow trout)0.03 - 0.19 mg/lNOECSodium chlorideExposuretime96 h0.01 - 0.1 mg/l28 dflowthroughtest LC50Lepomis macrochirus5,840 mg/l96 hNOECPimephales promelas(fathead minnow)Fish252 mg/l33 d35 - 189mg/l96 hOncorhynchus mykiss(rainbow trout)260 - 310mg/l96 hExposuretime48 hSodium hydroxideLC50Sodium silicateLC50Toxicity to aquatic invertebratesComponentsEnd pointSpeciesValueSodium hypochloritestatic testEC50Daphnia magna (Waterflea)0.033 0.044 mg/l8/13

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200DRANO LIQUID DRAIN CLEANERVersion 1.2Print Date 03/04/2015Revision Date 02/24/2015SDS Number 350000004298Sodium chloridestatic testEC50Daphnia magna (Waterflea)48 hNOECDaphnia pulex314 mg/l21 dSodium hydroxideEC50Daphnia magna (Waterflea)40.4 mg/l48 hSodium silicatestatic testEC50Daphnia magna (Waterflea)1,700 mg/l48 hEnd pointSpeciesValue340.7469.2 mg/lToxicity to aquatic plantsComponentsSodium hypochloriteEC50Skeletonema costatum0.095 mg/lExposuretime72 hSodium chlorideIC50Algae3,014 mg/l72 hDesmodesmussubspicatus (green algae) 345.4mg/l72 hSodium hydroxideSodium silicatePersistence and degradabilityComponentSodium hypochloriteSodium chlorideSodium hydroxideSodium silicateNo dataavailableEC50BiodegradationNo data availableNo data availableNo data availableNo data availableBioaccumulative potential9/13ExposuretimeSummary

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200DRANO LIQUID DRAIN CLEANERVersion 1.2Print Date 03/04/2015Revision Date 02/24/2015SDS Number 350000004298ComponentBioconcentrationfactor (BCF)No data available1.09 QSAR0.89 estimatedNo data availablePartition Coefficient nOctanol/water (log)-3.420.54-1.38No data availableComponentEnd pointValueSodium hypochloriteSodium chlorideSodium hydroxideSodium silicateNo data availableNo data availableNo data availableNo data availableSodium hypochloriteSodium chlorideSodium hydroxideSodium silicateMobilityPBT and vPvB assessmentComponentSodium hypochloriteResultsNot fulfilling PBT and vPvB criteriaSodium chlorideNot fulfilling PBT and vPvB criteriaSodium hydroxideNot fulfilling PBT and vPvB criteriaSodium silicateNot fulfilling PBT and vPvB criteriaOther adverse effects:None known.13. DISPOSAL CONSIDERATIONSConsumer may discard empty container in trash, or recyclewhere facilities exist.14. TRANSPORT INFORMATIONPlease refer to the Bill of Lading/receiving documents for up-to-date shipping information.10/13

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200DRANO LIQUID DRAIN CLEANERVersion 1.2Print Date 03/04/2015Revision Date 02/24/2015SDS Number 350000004298UN numberUN propershipping nameTransport hazardclass(es)Packing groupEnvironmentalhazardsSpecialprecautions foruserLand transport1760UN 1760 CORROSIVELIQUID, N.O.S(Sodium hypochlorite),8, III8IIISea transport1760UN 1760CORROSIVELIQUID, N.O.S(Sodiumhypochlorite), 8, III8Air transport1760UN 1760 CORROSIVELIQUID, N.O.S (Sodiumhypochlorite), 8, IIIIIIIII--Limited quantitiesderogation may beapplicable to thisproduct, please checktransport documents.Limited quantitiesderogation may beapplicable to thisproduct, pleasecheck transportdocuments.8Limited quantitiesderogation may beapplicable to thisproduct, please checktransport documents.15. REGULATORY INFORMATIONNotification status:All ingredients of this product are listed or are excluded fromlisting on the U.S. Toxic Substances Control Act (TSCA)Chemical Substance Inventory.Notification status:All ingredients of this product comply with the New SubstancesNotification requirements under the Canadian EnvironmentalProtection Act (CEPA).California Prop. 65:This product does not contain any chemicals known to State ofCalifornia to cause cancer, birth defects, or any otherreproductive harm.11/13

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200DRANO LIQUID DRAIN CLEANERVersion 1.2Print Date 03/04/2015Revision Date 02/24/2015SDS Number 35000000429816. OTHER INFORMATIONHMIS RatingsHealth3Flammability0Reactivity0NFPA RatingsHealth3Fire0Reactivity0Special-This information is being provided in accordance with the Occupational Safety and Health Administration(OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces whereproduct use and frequency of exposure exceeds that established for the labeled consumer use.Further informationThis document has been prepared using data from sources considered to be technically reliable. It doesnot constitute a warranty, expressed or implied, as to the accuracy of the information contained herein.Actual conditions of use are beyond the seller's control. User is responsible to evaluate all availableinformation when using product for any particular use and to comply with all Federal, State, Provincialand Local laws and regulations.Prepared bySC Johnson Global Safety Assessment &Regulatory Affairs (GSARA)12/13

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200DRANO LIQUID DRAIN CLEANERVersion 1.2Print Date 03/04/2015Revision Date 02/24/2015SDS Number 35000000429813/13

DRANO LIQUID DRAIN CLEANER Version 1.2 Print Date 03/04/2015 Revision Date 02/24/2015 SDS Number 350000004298 1/13 1. PRODUCT AND COMPANY IDENTIFICATION Product information Product name : DRANO LIQUID DRAIN CLEANER Recommended use : Drain Cleaner Manufacturer, importer, supplier : S.C. Johnson & Son, Inc. 1525 Howe Street